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Geochemistry and Basin Modeling

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Bulletin Article

7963
 
Organic-carbon–rich shales of the lower Marcellus Formation were deposited at the toe and basinward of a prograding clinothem associated with a Mahantango Formation delta complex centered near Harrisburg, Pennsylvania. Distribution of these organic-carbon–rich shales was influenced by shifts in the delta complex driven by changes in rates of accommodation creation and by a topographically high carbonate bank that formed along the Findlay-Algonquin arch during deposition of the Onondaga Formation. Specifically, we interpret the Union Springs member (Shamokin Member of the Marcellus Formation) and the Onondaga Formation as comprising a single third-order depositional sequence. The Onondaga Formation was deposited in the lowstand to transgressive systems tract, and the Union Springs member was deposited in the transgressive, highstand, and falling-stage systems tract. The regional extent of parasequences, systems tracts, and the interpreted depositional sequence suggest that base-level fluctuations were primarily caused by allogenic forcing—eustasy, climate, or regional thermal uplift or subsidence—instead of basement fault reactivation as argued by previous workers. Paleowater depths in the region of Marcellus Formation black mudrock accumulation were at least 330 ft (100 m) as estimated by differences in strata thickness between the northwestern carbonate bank and basinal facies to the southeast. Geochemical analysis indicates anoxic to euxinic bottom-water conditions. These conditions were supported by a deep, stratified basin with a lack of circulation.
5777
 

The influence of moisture, temperature, coal rank, and differential enthalpy on the methane (CH4) and carbon dioxide (CO2) sorption capacity of coals of different rank has been investigated by using high-pressure sorption isotherms at 303, 318, and 333 K (CH4) and 318, 333, and 348 K (CO2), respectively. The variation of sorption capacity was studied as a function of burial depth of coal seams using the corresponding Langmuir parameters in combination with a geothermal gradient of 0.03 K/m and a normal hydrostatic pressure gradient. Taking the gas content corresponding to 100% gas saturation at maximum burial depth as a reference value, the theoretical CH4 saturation after the uplift of the coal seam was computed as a function of depth. According to these calculations, the change in sorption capacity caused by changing pressure, temperature conditions during uplift will lead consistently to high saturation values. Therefore, the commonly observed undersaturation of coal seams is most likely related to dismigration (losses into adjacent formations and atmosphere). Finally, we attempt to identify sweet spots for CO2-enhanced coalbed methane (CO2-ECBM) production. The CO2-ECBM is expected to become less effective with increasing depth because the CO2-to-CH4 sorption capacity ratio decreases with increasing temperature and pressure. Furthermore, CO2-ECBM efficiency will decrease with increasing maturity because of the highest sorption capacity ratio and affinity difference between CO2 and CH4 for low mature coals.

Bulletin E P Note

7959
 

The petroleum trap for the Athabasca oil sands has remained elusive because it was destroyed by flexural loading of the Western Canada Sedimentary Basin during the Late Cretaceous and Paleocene. The original trap extent is preserved because the oil was biodegraded to immobile bitumen as the trap was being charged during the Late Cretaceous. Using well and outcrop data, it is possible to reconstruct the Cretaceous overburden horizons beyond the limit of present-day erosion. Sequential restoration of the reconstructed horizons reveals a megatrap at the top of the Wabiskaw-McMurray reservoir in the Athabasca area at 84 Ma (late Santonian). The megatrap is a four-way anticline with dimensions 285 x 125 km (177 x 78 mi) and maximum amplitude of 60 m (197 ft). The southeastern margin of the anticline shows good conformance to the bitumen edge for 140 km (87 mi). To the northeast of the anticline, bitumen is present in a shallower trap domain in what is interpreted to be an onlap trap onto the Canadian Shield; leakage along the onlap edge is indicated by tarry bitumen outliers preserved in basement rocks farther to the northeast. Peripheral trap domains that lie below the paleospillpoint, in northern, southern, and southwestern Athabasca, and Wabasca, are interpreted to represent a late charge of oil that was trapped by bitumen already emplaced in the anticline and the northeastern onlap trap. This is consistent with kimberlite intrusions containing live bitumen, which indicate that the northern trap domain was charged not before 78 Ma. The trap restoration has been tested using bitumen-water contact well picks. The restored picks fall into groups that are consistent both with the trap domains determined from the top reservoir restoration and the conceptual charge model in which the four-way anticline was filled first, followed by the northeastern onlap trap, and then the peripheral trap domains.

Explorer Article

8582
 

A three-day international conference honoring the life and work of the late AAPG Honorary member David Roberts, entitled “Basin Dynamics and Petroleum Systems: Geophysics, Structure, Stratigraphy, Sedimentology and Geochemistry.” will be held April 14-16 at Royal Holloway University, London, England.

8486
 

Robert G. Loucks, a senior research scientist at the Bureau of Economic Geology, University of Texas at Austin, is one of this year’s Robert R. Berg Outstanding Research Award winners. 

8060
 

Energized by the recent Statoil ASA-operated Bay du Nord light oil discovery in Newfoundland’s offshore Flemish Pass Basin, earth scientists are gearing up to host the fourth Atlantic Realm Conjugate Margins Conference in St. John’s, Newfoundland, Aug. 20-22.

8045
 

Oklahoma! As-yet unlocked SCOOP and STACK plays have plen’y of room for maturation and development.

3784
 

"Breakthrough elegance": ExxonMobil geologists Jeff Ottmann and Kevin Bohacs shared their highly-coveted knowledge on sweet spots and producibility thresholds at a recent Geosciences Technology Workshop on Unconventional Reservoir Quality.

Explorer Emphasis

8065
 

Seismic data is an important asset in finding sweet spots in shale plays, as AAPG member Joanne Wang discussed at a recent workshop.

3789
 

The Final Frontier: The Arctic Circle’s vast, untapped treasures of oil and gas resources beckon explorers to boldly go, despite the daunting technical, political and environmental challenges.

Forum

Oklahoma City Oklahoma United States 29 May, 2014 29 May, 2014 3810
 
Oklahoma City, Oklahoma, United States
29 May 2014
Join us for an intensive one-day forum which will focus on optimizing the exploration and development of the Woodford Shale. We're looking at recent findings in geochemistry and geomechanics to understand how best to drill and complete the reservoir, and also where the productive limits may be.

Short Course

Houston Texas United States 02 December, 2014 04 December, 2014 1516
 
Houston, Texas, United States
2-4 December 2014

Here is an introduction to the tools and techniques that geologists and geophysicists use to locate gas and oil, that drillers use to drill the wells and that petroleum engineers use to test and complete the wells and produce the gas and oil. Exercises throughout the course provide practical experience in well log correlation, contouring, interpretation of surface and subsurface, contoured maps, seismic interpretation, well log interpretation, and decline curve analysis.

Tulsa Oklahoma United States 07 October, 2014 09 October, 2014 1511
 
Tulsa, Oklahoma, United States
7-9 October 2014

Here is an introduction to the tools and techniques that geologists and geophysicists use to locate gas and oil, that drillers use to drill the wells and that petroleum engineers use to test and complete the wells and produce the gas and oil. Exercises throughout the course provide practical experience in well log correlation, contouring, interpretation of surface and subsurface, contoured maps, seismic interpretation, well log interpretation, and decline curve analysis.

Houston Texas United States 19 August, 2014 21 August, 2014 1509
 
Houston, Texas, United States
19-21 August 2014

Here is an introduction to the tools and techniques that geologists and geophysicists use to locate gas and oil, that drillers use to drill the wells and that petroleum engineers use to test and complete the wells and produce the gas and oil. Exercises throughout the course provide practical experience in well log correlation, contouring, interpretation of surface and subsurface, contoured maps, seismic interpretation, well log interpretation, and decline curve analysis.

Denver Colorado United States 03 June, 2014 05 June, 2014 1505
 
Denver, Colorado, United States
3-5 June 2014

Here is an introduction to the tools and techniques that geologists and geophysicists use to locate gas and oil, that drillers use to drill the wells and that petroleum engineers use to test and complete the wells and produce the gas and oil. Exercises throughout the course provide practical experience in well log correlation, contouring, interpretation of surface and subsurface, contoured maps, seismic interpretation, well log interpretation, and decline curve analysis.

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