American Association of Petroleum Geologists (AAPG)
We use sediment ages and mercury (Hg) concentrations to estimate past and future concentrations in the South River, Virginia, where Hg was released between 1930 and 1950 from a manufacturing process related to nylon production. In a previous study, along a 40 km (25 mi) reach, samples were collected from 26 of 54 fine-grained deposits that formed in the lee of large wood obstructions in the channel and analyzed for grain size, Hg concentration, and organic content. We also obtained radiometric dates from six deposits. To create a history that reflects the full concentration distribution (which contains concentrations as high as 900 mg/kg [900 ppm]), here, we treat the deposits as a single reservoir exchanging contaminated sediments with the overlying water column, and assume that the total sediment mass in storage and the distribution of sediment ages are time invariant. We use reservoir theory to reconstruct the annual history of Hg concentration on suspended sediment using data from our previous study and new results presented here. Many different reconstructed histories fit our data. To constrain results, we use information from a well-preserved core (and our estimate of the total mass of Hg stored in 2007) to specify the years associated with the peak concentration of 900 mg/kg. Our results indicate that around 850 kg (1874 lb) of Hg was stored in the deposits between 1955 and 1961, compared to only 80 kg (176 lb) today. Simulations of future Hg remediation suggest that 100-yr timescales will be needed for the South River to remove Hg-contaminated sediments from the channel perimeter through natural processes.